CM3这个内核是大小端可配置的: The processor contains a configuration pin, BIGEND, that enables you to select either the little-endian or BE-8 big-endian format. This configuration pin is sampled on reset. You cannot change endianness when out of reset. STM32是固定配置为小端的:RM0008 Reference manual The bytes are coded in memory in Little Endian format. The lowest numbered byte in a word is considered the word’s least significant byte and the highest numbered byte the most significant.